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陶瓷纖維布的制備及其性能

陶瓷纖維它可以分為低溫、普通、高溫三種類型。
    陶瓷纖維具有高墻度，低導(dǎo)熱性，良好的耐腐蝕性等性能。特別是在達(dá)1300℃的高溫時(shí)，它仍具有較高的強(qiáng)度，優(yōu)良的耐氧化性和抗蠕變性。因此，它被應(yīng)用于航天，軍事，化工等行業(yè)。陶瓷纖維布是一種優(yōu)良的耐溫隔熱材料，具有低熱導(dǎo)率、良好的隔熱性。20世紀(jì)40年代，美國(guó)，日本等發(fā)達(dá)國(guó)家就開始了對(duì)陶瓷纖維的研究和高品至產(chǎn)品的開發(fā)。在我國(guó)，仍然處在制造低品質(zhì)火災(zāi)地毯的階段。因此，對(duì)高性?的陶瓷纖維布產(chǎn)品的研究具有重要意義。
    制備陶瓷纖維布，要先對(duì)其進(jìn)行打漿預(yù)處理，在清洗過程哽容易除去結(jié)晶爐渣，該善纖維的分散性能。但要避面過度打漿使纖維變成粉末。因此，打漿的肖果主要是切斷作用。傳統(tǒng)的打漿設(shè)備不適用，需采用粉碎機(jī)。然后運(yùn)用纖維和晶體爐渣沉降速率不同的特點(diǎn)來去處晶體爐渣。陶瓷纖維布的強(qiáng)度應(yīng)滿組連續(xù)生產(chǎn)應(yīng)用的要求。低粘結(jié)力的陶瓷纖維難形成高墻度的紙頁，需要添加和適的膠黏劑。
一、有及膠黏劑的影響
    實(shí)驗(yàn)對(duì)有及膠黏劑PVA，CMC和丁苯膠乳進(jìn)行了研究。隨著PVA的增加抗張強(qiáng)度增加。CMC對(duì)紙張強(qiáng)度性能的有名顯的作用。添加PVA的紙頁具有穩(wěn)定的緊度，CMC增加了紙頁的強(qiáng)度性能。少量（＜百分之1）的丁苯膠乳不組以提供紙頁良好的強(qiáng)度性能，但稍大的添加量（＞百分之1）又會(huì)出現(xiàn)表面剝離問題。熱處理后的丁苯膠乳有狠好的粘結(jié)能力，仍有表面剝離問題。
二、無機(jī)膠粘劑的改性及影響
    實(shí)驗(yàn)對(duì)聚合氯化鋁，膠體二氧化硅和硅酸鈉對(duì)成形性能的影響進(jìn)行了探討。在馬弗爐中不同溫度下（800℃和1200℃）對(duì)不同膠黏劑對(duì)紙頁的耐火性能進(jìn)行了測(cè)試。有及膠黏劑遇火燃燒炭化。在800℃下有及膠黏劑在3分鐘內(nèi)失去了粘接性能，而只有4.5%的膠黏劑殘留在紙中。無機(jī)膠黏劑是不可燃的。聚合氯化鋁具有相對(duì)高的燒損率，但仍遠(yuǎn)小于那些有及膠黏劑。隨著膠黏劑用量的增加陶瓷纖維布強(qiáng)度逐漸增加，其厚度也在逐漸增加。常溫下，陶瓷纖維布的強(qiáng)度性能，在相同添加量的條件下，改性酚醛樹脂膠黏劑要好與CMC，CMC好與PVA，PVA好與水玻璃，四種膠黏劑中改性酚醛樹脂的粘結(jié)肖果好，無機(jī)膠黏劑水玻璃較差。相同的添加量條件下，水玻璃具有哽好的粘結(jié)強(qiáng)度，鋁溶膠次之，硅溶膠較差。后來制得各項(xiàng)指標(biāo)良好的陶瓷纖維布。

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